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Creators/Authors contains: "Piyush Haluai, Tara M."

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  1. Surface strain often controls properties of materials including charge transport and chemical reactivity. Localized surface strain is measured with atomic resolution on (111) ceria nanoparticle surfaces using environmental transmission electron microscopy under different redox conditions. Density functional theory (DFT) coupled with TEM image simulations have been used to interpret the experimental data. Oxygen vacancy creation/annihilation processes introduce strain at the surface and near surface regions of the cation sublattice. Both static and fluxional strainmaps are generated from high resolution images recorded under varying reducing conditions. While fluxional strain is highest at locations associated with unstable vacancy sites, highly inhomogeneous static strain fields comprising of alternating tensile/compressing strain is seen at the surface and subsurfaces linked to the presence of stable oxygen vacancies. Interestingly, both stable and unstable oxygen vacancies are found within a few atomic spacings of each other on the same surface. The static strain pattern depends on the ambient environment inside the TEM. 
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